J.R. S. answered 12/12/19
Ph.D. University Professor with 10+ years Tutoring Experience
The reaction as given is
Na2S2O3 + AgBr ==> NaBr + Na3[Ag(S2O3)2] (note you wrote it incorrectly in the question - be careful)
Step 1: Balance the equation
2Na2S2O3 + AgBr ==> Na3[Ag(S2O3)2] + NaBr
Step 2: Calculate moles of AgBr present
42.7 g AgBr x 1 mole AgBr/187.8 g = 0.227 moles AgBr
Step 3: Use the mole ratio of the balanced equation to calculate moles Na2S2O3 needed
The mole ratio of Na2S2O3 to AgBr is 2:1
0.227 moles AgBr x 2 moles Na2S2O3 / mole AgBr = 0.454 moles Na2S2O3 needed (answer to part 1)
Step 4: Use the mole ratio and molar mass of NaBr to calculate mass of NaBr produced
0.227 moles AgBr x 1 mol NaBr/mol AgBr x 103 g NaBr/mol NaBr = 23.4 g NaBr produced (answer to part 2)