J.R. S. answered 12/07/19
Ph.D. University Professor with 10+ years Tutoring Experience
The question asks to find a volume after a change in pressure. There is no mention of the temperature, so one must assume this is constant. In this case, we are dealing with Boyles Law: P1V1 = P2V2
P1 = initial pressure =1.00 atm
V1 = 44.0 L
P2 = 1.00 atm - 0.04 atm = 0.96 bar (assuming 1 bar = 1 atm and a decrease of 40.0 mbar = 0.040 atm)
V2 = ?
V2 = P1V1 / P2 = (1.00 atm)(44.0 L) / 0.96 atm
V2 = 45.8 L
(note: the unit of bar is not a recognized standard unit of pressure. One bar is very close to 1 atm, so hopefully the assumption used in the above calculation is acceptable)