J.R. S. answered 12/03/19
Ph.D. University Professor with 10+ years Tutoring Experience
First, when liquid copper changes from liquid to solid, energy will be liberated or released to the surroundings as it is an exothermic process. So, the answer will have a negative sign.
q = m∆Hfusion
q = heat = ?
m = mass = 3.0 moles Cu x 63.55 g/mol = 190.65 g (converted to grams to be consistent with units for ∆Hf)
∆Hf = 209 J/g
q = (190.65 g)(209 J/g) = 39,846 Joules
Rounding to 2 significant figures (based on 3.0 mol) and designating it as exothermic, we have an answer of....
-40,000 joules