J.R. S. answered 11/18/19
Ph.D. University Professor with 10+ years Tutoring Experience
2 Na+ + 2H2O ==> 2NaOH + H2 ... balanced equation
Since it is at STP, we know that 1 mole of gas (ideal) = 22.4 liters. So, find out how many moles of H2 gas is represented by 66 ml, then convert that to moles of Na, and finally to grams of Na.
moles of H2 gas:
66 ml H2 x 1 L/1000 ml x 1 mol/22.4 L = 0.002946 moles H2
moles Na to generate 0.002946 moles H2:
0.002946 moles H2 x 2 moles Na+ / mole H2 = 0.005893 moles Na+
mass of Na+ needed:
0.005893 moles Na+ x 22.99 g/mole = 0.135 g = 0.14 g Na+ (to 2 significant figures)