The mean of a binomial random variable is E(X) = np, where n is the number of events and p is the probability of each event occurring. The variance is Var(X) = np( 1 - p), and the standard deviation is the square root of the variance.
So, in this case, the probability of a girl is 0.5, and there are 36 couples, or 36 events.
Var(X) = 36·0.5(1 - 0.5) = 9.
Then the standard deviation is √9 = 3.