Normally,
Chromium(III) hydroxide react with sodium hydroxide to produce sodium hexahydroxochromate(III). Sodium hydroxide - concentrated solution.
But for calculation purpose if the reaction given in problem is what it is. Please read answers to your questions below.
Cr(OH)3+ NaOH-->NaCrO2 +2H2O
1 mole of Cr(OH)3 + 1 mole of NaOH will produce 1 mole of NaCrO2
Here we first need to find molar mass of Cr(OH)3 and NaCrO2
Molar mass of Cr(OH)3
Cr+3 (O)+ 3*(H)
=51.996+3*(15.999)+3(1.008) =103.017 ≅ 103
Molar Mass of NaCrO2
Na+Cr+2*(O)
=22.990+51.996+2*(15.999) = 106.984 ≅107
Mole of Cr(OH)3
Mole = weight in gram / Molar mass
=83.3 g of Cr(OH)3/ 103 ( molar mass of Cr(OH)3)
=.8087 mole of Cr(OH)3
Back to equation
Cr(OH)3+ NaOH-->NaCrO2 +2H2O
mole of Cr(OH)3 = mole of NaCrO2
.8087 mole of Cr(OH)3 =.8087 mole of NaCrO2
we need answers in Gram thus, we will need to multiply mole by molar mass to get the gram NaCrO2
.8087 mol of NaCrO2 * 107gram/mol = 86.53 grams of NaCrO2
Checking significant number is very important when calculating any chemistry problems
Initially the weight given in three significant number, thus our answer should be in three significant number.
That leave us with final answer 86.5g of NaCrO2 will be produce from 83.3g of Cr(OH)3.