Check out your unit circle. (Google "unit circle" if you don't have one, and get in touch to video chat if you don't understand where it comes from.) The (x,y) coordinates at each angle are the cosine and sine of that angle.
You'll see that at 120o, or 2π/3 and at 240o, or 4π/3, the x-coordinate is -1/2. Those are the two angles you start with. In degrees, add or subtract multiples of 360o from either one to get another answer, as that will take you around the circle another time/s. For example, since 120o works, so will (120+360)=480o, (120+360+360) = 840o, and (120-360)= -240o.
You can do the same with radians: Instead of adding or subtracting multiples of 360o, add or subtract multiples of 2π. Since the original angles are measured in thirds of pi, convert 2π to a fraction with 3 in the denominator: 2π = 6π/3. Here are three solutions in addition to 4π/3: (4π/3 - 6π/3)=-2π/3, (4π/3 -6π/3 - 6π/3)= -8π/3, and (4π/3 +6π/3)= 10π/3. You can add or subtract 2π as many times as you want from either 4π/3 or 2π/3 to get infinitely more answers.
I hope that helps! If you're still confused, or if you're not super sure why or how the unit circle works, PLEASE get in touch! It's really fundamental to everything in trigonometry!
Happy studies!
Liz