J.R. S. answered 06/27/19
Ph.D. University Professor with 10+ years Tutoring Experience
Osmotic pressure (π) = MRT
M = molarity = moles/liter = 85.0 g x 1 mol/180g/0.525 L = 0.899 M
R = gas constant = 0.0821 Latm/Kmol
T = temperature in K = 25.0 + 273 = 298K
π = (0.899 M)(0.0821 Latm/Kmol)(298K) = 21.99 atm = 22.0 atm (to 3 significant figures)