J.R. S. answered 06/23/19
Ph.D. University Professor with 10+ years Tutoring Experience
Don’t be frustrated. Look closely at the balanced equation.
N2 + 3H2 ==> 2NH3. The equation you present is incorrect. Maybe that’s why you’re having trouble.
It tells you that TWO moles of NH3 are produced from ONE mole of N2. We can use dimensional analysis to find moles NH3 made from 21 moles of N2.
21 moles N2 x 2 moles NH3/mole N2 = 42 moles NH3
Looking at it another way, the correctly balanced equation tells you that the moles of NH3 is TWICE the number of moles of N2 as the ratio of NH3 to N2 is 2:1