y = mx + b, with m being the slope. The steepness is the ratio between the rise vs the run. If it goes up/down faster than left/right, it's steeper. Think of a hill.
The slope with the highest absolute value (distance from 0, thus always positive) has the steepest slope. A slope of -100 is steeper than 1/4, because the first rises or falls 100 for every 1 it goes left or right, whereas the second goes up or down 1 for every 4 it goes left or right.
Hope this helps!