J.R. S. answered 05/31/19
Ph.D. University Professor with 10+ years Tutoring Experience
a). Formula weight of KCl = 39.1 g/mol
b). Mass of KCl = 1.23 moles x 39.1 g/mol = 48.09 g = 48.1 g
c). % by mass of KCl: The total mass of solution = 48.1 g (KCl) + 1000.0 g water = 1048.1 g. Percent by mass KCl = mass KCl/total mass (x100%) = 48.1/1048.1 (x100%) = 4.59%
d). Molarity of KCl = moles KCl/liter of solution. If we assume that the KCl did not increase the volume (which is probably not a valid assumption), then you have 1.23 moles KCl in 1000 g and since 1 g = 1 ml, that's the same as 1.23 moles KCl/1000 ml = 1.23 mole/L = 1.23 M. If the question meant to ask for the molality (not molarity), then it would be moles KCl/Kg water = 1.23 moles/1 kg = 1.23 molal.