J.R. S. answered 05/23/19
Ph.D. University Professor with 10+ years Tutoring Experience
Use the Nernst equation. Since no temperature is given in the problem, assume it to be 25ºC and use a modification of the Nernst equation for 25ºC which is Ecell = Eºcell - 0.0951/n log Q where n is the number of electrons transferred. You'll need to look up the standard reduction potentials for Zn and Cl and calculate the Eº. Since you are given the Ecell as 2.21 V, and Cl concentration of 0.1 M, you can solve for log Q and hence for [Zn].