Oh yes! Any point you choose. They are all potential vertices.
What I mean is that since a line has an infinite number of points, they are all potential vertices. In terms of your particular problem: A line is always defined (named) after 2 points on it. An angle is always named after 3 points (the first letter represents a point on a ray, the middle point is the vertex, and the last letter is a point on the other ray). So in your angle, the vertex is N. But, since a straight angle is essentially a line, you can just pick 2 points to be on the rays and any point in-between these 2 points to represent a vertex (but there can only be one vertex for each angle you create).
I hope that makes sense.