J.R. S. answered 05/14/19
Ph.D. University Professor with 10+ years Tutoring Experience
As with the previous questions, start with a balanced equation:
S + 3F2 ==> SF6
Find moles of each reactant:
moles S = 3.5 g S x 1 mol/32 g = 0.109 moles S
moles F2 = 4.5 g x 1 mol/38 g = 0.118 moles F2 (this is limiting since you need 3 moles F2 for each 1 mole of S, and thus there isn't enough F2)
Find theoretical yield of SF6:
0.118 moles F2 x 1 mole SF6/3 moles F2 x 146 g/mole SF6 = 5.7 g SF6
Excess reactant is S, and the mass remaining is...
0.118 moles F2 x 1 mole S/3 moles F2 = 0.0393 moles S used up.
mass remaining = 0.109 moles - 0.0393 moles = 0.0697 moles S x 32 g/mole = 2.2 g S left over.