ἀ - clean breathing tells you there is no h sound [a]
ἁ - rough breathing tells you there is an h sound [ha]
ά - acute tells you that the word's stress occurs on that syllable [á]
ὰ - grave tells you that the word's stress occurs on that syllable while not completing the tone [a]
ᾶ - circumflex tells you that the word's stress occurs on the first half of the long vowel [áa]