
William W. answered 02/22/19
Math and science made easy - learn from a retired engineer
The key element here is to realize that all the heat given off by the iron is absorbed by the calorimeter but not all of it goes into the water (some is lost to the calorimeter itself which is actually what we are trying to find).
So Qiron = Qwater + Qcalorimeter
Another key thing is that the final temperature of the iron will be the same as the final temperature of the water.
The standard equation for heat capacity is Q = mCΔT so for the water Q = 135*4.184*(30-25) = 2824.2
For the Iron Q = 100*0.444*(30-100) = - 3108 but we can drop the sign because the heat given off is the same as the heat taken in by the water and calorimeter
So 3108 = 2824.2 + Qcalorimeter
Qcalorimeter = 3108 - 2824.2 = 283.8j
But the calorimeter went up in temp by 5 degrees so to get C in J/degree divide the 283.8j by the 5 degrees C to get 56.76 J/°C and using 3 sig figs it becomes 56.8 J/°C