J.R. S. answered 02/12/19
Ph.D. University Professor with 10+ years Tutoring Experience
Easiest to do these problems in steps, noting that methylene chloride (mc) freezes/melts at -94.8ºC and boils/vaporizes at 40.0ºC. Also, note different units of temperature that are given in this problem (sneaky).
Let us first convert these so they are all the same.
T(°C) = (T(°F) - 32) × 5/9
ºC = (-171.4F - 32) x 5/9 = -113ºC = initial temperature
333K - 273 = 60ºC = final temperature
Then we use q = mC∆T when there is no phase change, and q = m∆H when there is a phase change. Note that since we are using ∆T (i.e. change in temp) the units of K or C don't matter.
Step 1. heat needed to raise temp of 20 g mc from -113º to -94.8º = q = (m)(C)(∆T) = (20g)(1.21J/g/º)(18.2º) = 440 J
Step 2. heat needed to melt 20 g mc at -94.8º = q = m∆Hf = (20g)(73.40J/g) = 1468 J
Step 3. heat needed to raise temp of 20 g mc from -94,8º to 40º = q = (m)(C)(∆T) = (20g)(1.21J/g/º)(134.8º) = 3262 J
Step 4. heat needed to vaporize 20 g mc at 40º = q = m∆Hvap = (20g)(334.35 J/g) = 6687 J
Step 5. heat needed to raise temp of 20 g mc from 40º to 60ºC = q = (m)(C)(∆T) = (20g)(0.608J/g/º)(20º) = 243 J
Add up all the joules to get the total amount of energy needed:
440J + 1468J + 3262J + 6687J + 243J = 12,100 J

J.R. S.
02/12/19
Ashley H.
Thank you very much J.R. I actually did everything right but was concerned it was not correct. The k and °C were throwing me off.02/12/19