J.R. S. answered 01/02/19
Ph.D. University Professor with 10+ years Tutoring Experience
These can generally be distinguished by melting and boiling points, strength and conductivity. A giant ionic compound is one where there is a metal and non metal and the metal donates the electron(s) and non metal accepts the electron(s) leaving a cation and anion. These are attracted to form a large lattice structure. Melting and boiling points are high and they conduct a current. Examples: sodium chloride (NaCl), magnesium chloride (MgCl2), etc.
A giant covalent compound is one in which a lot of non metal atoms are joined to other adjacent atoms by covalent bonds (sharing electrons) and arranged to form a giant lattice structure. These have very high melting and boiling points (higher than giant ionic) and they generally do not conduct a current (graphite being an exception). Example: graphite, diamond.
A simple molecular structure is just a covalent molecule where atoms are joined by covalent bonds (sharing electrons) but do not form a large lattice structure. The have lower melting and boiling points and generally do not conduct a current. Examples: methane, ethane, glucose, etc.