J.R. S. answered 12/05/18
Ph.D. University Professor with 10+ years Tutoring Experience
KO2 (potassium superoxide) is not a typical compound encountered in introductory chemistry. I'll assume it to be correct and proceed.
4KO2(s) + 2H2O(l) ===> 4KOH(s) + 3O2(g)
WORK IN MOLES FIRST, THEN CONVERT TO GRAMS
moles of KO2 present = 34.6 g KO2 x 1 mole/71.10 g = 0.4866 moles
moles of H2O present = 34.6 g H2O x 1 mole/18 g = 1.922 moles
Which reactant is limiting? Easiest way is to divide each by it's coefficient and see which is smaller.
0.4866/4 = 0.122 and 1.922/2 = 0.961 so KO2 IS LIMITING and determines KOH formation
moles of KOH theoretically formed = 0.4866 moles KO2 x 4 moles KOH/4 moles KO2 = 0.4866 moles KOH
mass of KOH = 0.4866 moles KOH x 56.1 g/mole = 27.29 g = 27.3 g (to 3 sig. figs.)