Ishwar S. answered 11/28/18
University Professor - General and Organic Chemistry
CH3COOH (aq) <==> H+ (aq) + CH3COO- (aq)
CH3COOH is acetic acid, which is a weak monoprotic acid. It dissociates only partially in an aqueous solution to form hydrogen ions and acetate ions. As a result, the acid dissociation reaction is written as an equilibrium reaction. First, we need to setup an ICE table to determine the concentration of [H+] from the initial concentration of the acid (0.25 mol L-1), and the Ka value (1.74 x 10-5).
CH3COOH (aq) <==> H+ (aq) + CH3COO- (aq)
I: 0.25 mol L-1 0 0
C: -x +x +x
E: (0.25 - x) x x
Since Ka is a small # (~10-5), we will assume that the value of x for the change in the equilibrium concentration of CH3COOH is negligible.
Ka = [H+] [CH3COO-] / [CH3COOH] = 1.74 x 10-5
(x) (x) / 0.25 = 1.74 x 10-5
x2 = 1.74 x 10-5 x 0.25
x2 = 4.35 x 10-6
x = √4.35 x 10-6 = 2.1 x 10-3 mol L-1 (rounded to 2 significant figures)
x = [H+] = 2.1 x 10-3 mol L-1
pH = - log [H+] = - log 2.1 x 10-3 = 2.68