If we square both sides of the equation, we get
(cotA+1/cotA)(cotA+1/cotA)=1^2
cot2A+1+1+1/cot2A=1
Subtract 2 to get:
cot2A+1/cot2A=-1
So we have a sum of two squares (positive numbers) equal to a negative number. So your original equation is actually never true for real A.
But this makes sense: you're adding a number and its reciprocal. One of those must be greater than 1, and they must have the same sign.