J.R. S. answered 12/06/17
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mass % NaCl = mass NaCl/mass of solution (x100%)
Your question asks for the mass % of sodium chloride, but the problem says it is sodium carbonate. It makes no difference in this particular case, but if moles were involved, it would matter.
Solid solute = 2.27 g
total mass = 251.60 g (solute + solvent)
mass % of solute (NaCl or Na2CO3) = 2.27 g/251.60 g (x100%) = 0.902% by mass (to 3 significant figures)