J.R. S. answered 11/09/17
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So, this is a problem of recognizing stoichiometric relationships between reactants and products, and of mass to mole conversions. Essentially, you are given (or can calculate) the mass of Sb2S3 that you begin with, and are asked to find the mass of Sb produced as a final product. Since O2 is in excess, there is no need in this problem to find the limiting reactant. Also, you are already given the balanced equations, so no need to balance them. Let's begin.
1.00 kg ore x 0.232 = 0.232 kg of Sb2S3 as starting mass (corrected for 23%)
Finding moles Sb2S3:
0.232 kg Sb2S3 x 1000 g/kg x 1 mole/339.7 g = 0.683 moles Sb2S3
Finding moles Sb4O6 produced:
0.683 moles Sb2S3 x 1 mole Sb4O6/2 moles Sb2O3 = 0.342 moles Sb4O6
Find moles of Sb produced:
0.342 moles Sb4O6 x 4 moles Sb/1 moles Sb4O6 = 1.37 moles Sb
Find mass of Sb produced:
1.37 moles Sb x 121.8 g/ mole = 167 g Sb produced