J.R. S. answered 11/23/16
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Ch3COOH + NaOH ==> CH3COONa + H2O
Initially you have 0.100 mol of CH3COOH
You then add 20 ml of 1.0 M NaOH = 0.02 L x 1 mol/L = 0.02 moles NaOH.
This will more than neutralize ALL the CH3COOH, leaving 0.1 moles acetate and excess NaOH and no acetic acid.