Prabhakar S. answered 02/20/24
PhD in Chemistry with 30+ years of Teaching Experience.
Cleaner with a higher boiling point has stronger intermolecular forces (which can be dispersion, dipole-dipole or H-bonding). Polar substances exhibit dipole-dipole interactions or H-bonding. Therefore, if the high boiling point of the cleaner is NOT due to dispersion forces, cleaner and the polar substance can interact (develop intermolecular interaction) better with each other (participate/contribute in each others intermolecular forces), and help remove the polar substance more efficiently.