
Sean R. answered 07/31/23
Experienced Chemistry Tutor
To calculate the activity coefficient (γ) using the Debye-Hückel equation, we need to know the ionic strength (μ) of the solution and the size parameter (a) for the Zr4+ ion. The Debye-Hückel equation is given by:
log10(γ±) = -0.51 * z^2 * √(μ) / (1 + a √(μ))
where:
z = charge of the ion (in this case, z = +4 for Zr4+)
μ = ionic strength of the solution
a = size parameter of the ion
You provided the following values:
Zr charge (z) = +4
Size parameter (a) = 1.100
Ionic strength (μ) = 0.0297 M
Now let's calculate the activity coefficient:
log10(γ±) = -0.51 * (4)^2 * √(0.0297) / (1 + 1.100 * √(0.0297))
log10(γ±) = -0.51 * 16 * √(0.0297) / (1 + 1.100 * √(0.0297))
log10(γ±) = -0.51 * 16 * 0.1722 / (1 + 1.100 * 0.1722)
log10(γ±) = -0.51 * 16 * 0.1722 / (1 + 0.1894)
log10(γ±) = -0.51 * 16 * 0.1722 / 1.1894
log10(γ±) = -0.1412
Now, to find γ±, we need to take the antilog (10 raised to the power of -0.1412):
γ± = 10^(-0.1412)
γ± ≈ 0.7978
So, the activity coefficient (γ±) for Zr4+ ion in the given solution is approximately 0.7978.
Yash P.
Hi Sean, I see how you got your answer unfortunately this was also labeled to be wrong. It is wanting me to use a different debye-huckle equation that includes X and Zx which I am having trouble using07/31/23