To do this dimensional analysis calculation we need to first know the metric/common conversions for gallons & Liters and miles & kilometers. Looking these up we have 1 mile = 1.609 km & 1 gallon = 3.785 Liters
Since we want km as the answer, we'll start with that and put km in the numerator. Then, using D.A., we can set up the calculation as follows:
(1.609 km/1 mile) (35 miles/1 gallon) (1 gallon/3.785 Liters) 22 Liters.
Cancelling out the like terms results in km. Do the calculation now & you will get the correct answer (there's only 2 sig figs in the data, so the answer should be rounded accordingly to 2 sig figs.