To determine the heat absorbed by the bomb calorimeter, we can use the equation:
q = m × c × ΔT
where:
q is the heat absorbed (in Joules),
m is the mass of the substance (in grams),
c is the specific heat capacity of the substance (in J/gºC), and
ΔT is the change in temperature (in ºC).
First, let's calculate the heat absorbed by the iron sample:
m_iron = 57.28 g
c_iron = 0.450 J/gºC
ΔT_iron = (100.0 ºC - 20.63 ºC) = 79.37 ºC
q_iron = m_iron × c_iron × ΔT_iron
= 57.28 g × 0.450 J/gºC × 79.37 ºC
= 2045.29 J
Next, we'll calculate the heat absorbed by the water in the calorimeter:
m_water = 47.53 g
c_water = 4.184 J/gºC
ΔT_water = (23.59 ºC - 20.63 ºC) = 2.96 ºC
q_water = m_water × c_water × ΔT_water
= 47.53 g × 4.184 J/gºC × 2.96 ºC
= 596.95 J
Since the heat absorbed by the bomb calorimeter is equal to the heat released by the iron sample (assuming no heat loss to the surroundings):
q_bomb_calorimeter = -q_iron = -2045.29 J (negative sign because heat is released)
Therefore, the heat absorbed by the bomb calorimeter is approximately 2045.29 Joules.