Based on the information provided we needed to use the equation ∆T = Kfm where m is the molality. (This is how the molality value was obtained.)
Molality = moles of solute /kg solvent [ m = moles solute/kg solvent]
You were given 370.0 mL of benzene and the density of benzene 0.877 g/mL. With this information the mass of benzene can be calculated.
Mass of benzene used = 370.0 mL*0.877 g/mL = 324.5 g =0.3245 kg solvent
Substituting these values in the equation
[ m = moles solute/kg solvent] the moles of solute can be calculated
Moles of solute = 3.63 * 0.3245 = 1.18 moles solute
Hope this helps!