The balanced equation 4Na + O2 → 2Na2O tells us in moles that 4 moles of Na reacts with 1 moles of O2 to produce 2 moles of Na2O. The coefficients can be used to set up a relationship between the reactants/products. For the specific question 2 moles of Na2O will be produced from 4 moles of Na . With this relationship we can calculate how many moles of Na is required to produce ANY amount of Na2O..
(0.6 mol Na2O ) ( 4mol Na / 2 mol Na2O) = 1.2 mol Na gives the answer
Remember the coefficients from any equation can be written as a conversion factor and used in such a way as to obtain what is asked in your question.
Hope this helps!