Your equation is not balanced and you do not need it anyway. The correct balancing is put a 1 in front of the octane, use the C balance fo determine you need 8CO2, and use an H balance to determine you need 9H2O. The O balance tells you that you need 8(2) + 9 O or 25/2 O2.. Oh, I see what happened, you forgot to have a 2 in front of the octane (Personally, I prefer the form with one mole in front as it makes the equation per one mole of fuel - if you look up heats of combustion, they are referring to this form of the equation).
Anyway, all of the carbon in the octane goes exclusively to CO2, so you can just use grams of C as a tie-in:
500 g oct (96 g C/114 g oct)(44g CO2/12 g C)
You can use the usual 3-step stoichiometry calculation and the balance equation:
500 g oct(1 mole/114 g oct)(8 mole CO2/1 mole oct)(44g//1mole CO2)
Please consider a tutor. Take care.