Sodium hydroxide, NaOH, is a strong base meaning it completely dissociates:
NaOH ---> Na+ + OH- (stoichiometry of the balanced equation is 1 NaOH : 1 Na+ : 1 OH-).
So 1.80 x 10-4 M NaOH produces 1.80x10-4 M Na+ ions and 1.80x10-4 M OH- ions so we can use this concentration of OH- directly to find the pOH
pOH = -log[OH-] = -log(1.80 x 10-4) = 3.745
Knowing that pH + pOH = 14 then pH = 14 - pOH
pH = 14 - 3.745 = 10.255 (The pH > 7 which is what we expect for a basic solution so our answer makes sense.)
Hope this helps!