the balanced chemical equation tells you that the mole ratio here is 5 mol O2 for every 3 mol CO2 produced, meaning that to find the number of mole of O2 required you can take
0.75 mol CO2 x (5 mol O2 / 3 mol CO2) = 1.25 mol O2
1.25 moles of O2 gas are needed to produce 0.75 moles of CO2