Hi Ryan - happy to help. It is a series of conversions
First- moles of toluene to moles of CO2 (using the balanced chemical reaction).
Second - moles of CO2 to grams of CO2 (using molar mass of CO2 from the periodic table)
Note - I'm not using any analysis of sig. figs here....
0.05090 moles of Toluene x 7 moles of CO2. x. 44 g CO2 = 15.7 grams of CO2
1 mole Toluene 1 mole of CO2