Michael S. answered 08/05/26
B.S. in Chemistry, Indiana University; Organic Chem Teaching Intern
Co(s) + Cl2(g) → CoCl2(s)
It is already balanced as written: one Co on each side, two Cl on each side.
This is a synthesis (combination) reaction
A metal plus a nonmetal gives an ionic compound — the general form is A + B → AB. It is also a redox reaction: cobalt is oxidised from 0 to +2, and each chlorine is reduced from 0 to −1.
Getting the formula right is the actual work here
Chlorine reliably forms Cl−, so you need enough chloride to cancel the cobalt's charge. Cobalt is a transition metal with variable oxidation states — it forms both Co2+ and Co3+ — so you cannot read its charge off the group number the way you can for sodium or magnesium.
Direct reaction of the metal with chlorine gas gives cobalt(II) chloride, CoCl2. Two Cl− balance one Co2+.
Had the problem specified cobalt(III), the formula would be CoCl3 and the balanced equation would become:
2 Co(s) + 3 Cl2(g) → 2 CoCl3(s)
So watch for a Roman numeral in the compound name — with transition metals it is the only thing telling you the charge. (In practice CoCl3 is unstable and decomposes, which is part of why the direct reaction gives the II compound.)
Balancing, if you had started from CoCl2 unbalanced
Write the correct formulas first, then balance with coefficients. Never adjust a subscript to make an equation balance — changing CoCl2 to CoCl3 does not balance the equation, it changes the substance. Here the formulas happen to balance on their own.
Why you may have met this compound already: CoCl2 is the classic humidity indicator. Anhydrous CoCl2 is deep blue; absorbing water gives the hexahydrate CoCl2·6H2O, which is pink. That is the blue-to-pink paper in desiccant packs, and heating it drives the water back off and returns the blue — a reversible hydration, not a new synthesis.