
Antonio P. answered 02/27/22
Radioactive Chemist
When attempting to follow this logic yourself, pay attention to the sig figs, your units, and your math.
1). Fe2O3 --> oxygen is -2, -2*3 = -6 . Therefore Fe is Fe(III), being +2, +2*3=6. Compound is not negative or positive therefore this checks out, -6 + 6 = 0.
Molar Mass Fe(III) => 55.845 g/mol , Molar Mass Oxygen = 16. 55.845 * 2 + 3 * 16= Molar Mass hematite=159.69 g/mol. Weight Fraction of Fe(III) per mole hematite = (55.845*@2)/(159.69) = approx 0.699.
Weight fraction O per mole Hematite = 16*3 / 159.69 = approx .300.
69.9/100 = (6.9* 10^3)/x, where x= weight of total hematite.
2). Magnetite consists of 1 Fe(II) and 2 Fe(III). ( Molar Mass Fe(II) + 2(Molar Mass Fe(III) + 4(Molar Mass O)) = Molar mass magnetite --> approx 231.533 g/mol. (Molar Mass Fe(II) + 2*Molar Mass Fe(III))/ 231.533 = weight fraction of iron in magnetite. (weight fraction of iron * 100)/100 = (6.9*10^3)/x, where x = weight of total magnetite.
3). Molar Mass of Fe(II) / Molar mass siderite = weight fraction of iron in siderite. (Weight fraction of Iron * 100)/100=(6.9*10^3)/x where x is total weight of siderite