For part a, from the balanced equation you know that one mol of Fe(NO3)3 will produce 3 moles of Na(NO)3.
Using ratios, you can find that 7.45 moles of Fe(NO3)3 will produce (7.45 * 3) moles of Na(NO)3 = 22.4 moles.
For part b, first convert grams into moles: 7.45 g / 242 (g/mol) = 0.0308 moles of Fe(NO3)3. And like part a, you can calculate the moles of Na(NO)3 produced by multiplying by 3. The you can convert back to grams by multiplying by the molecular weight of Na(NO)3.