Here you will need to calculate/know the molar mass of sodium acetate NaC2H3O2 = 82.0 g/mole.
You need to also remember when given the molarity (eg. 0.171 M) this means that in 1 liter (1000 mL) of the solution in question there are 0.171 moles of the substance dissolved. Using this information you can calculate the grams of the solute (substance dissolved) needed to prepare 250 mL...
250 mL x ( 0.171 mol NaC2H3O2 ⁄ 1000 mL soln) x (82.0 g NaC2H3O2 ⁄ 1 mol NaC2H3O2) = 3.51 g
The second part involves techniques which are shared with you in the lab about preparing solutions using a volumetric flask and how to handle/ prepare glassware. Review that information...