Use Charles' Law, which applies when the pressure is held constant:
V1/T1 = V2/T2
Where:
- V1 = initial volume = 100 ml
- T1 = initial temp = 25c
- V2 = final volume = unknown
- T2 = final temp = 80c
V2 = V1*(T2/T1)
V2 = (100 ml)*(80c/25c) = 320 ml