The definition of Molar is moles/liter. We have (210.6g/180.16) or 1.169 moles of glucose. That is dissolved in 500 ml, or 0.5 liters. That means the concentration of the glucose solution is (1.169moles/0.5L) = 2.338 M (4 sig figs).
24.1 ml (0.0241L) of the 2.338M solution is dissolved in 250 ml (0.250L).
The moles of glucose in 24.1 ml: (2.338 moles/Liter)*(0.0241L) = 0.05634 moles
Then dilute the 0.05634 moles to 250 ml (0.250L): (0.05634 moles)/(.250L) = 0.2254M