Veronica J. answered 10/12/21
Double MSc Grad for Data Science, Bioinformatics, & Chemistry Tutoring
When asked a question like this, think about the definition of empirical formula. Empirical formula is the 'simplest (or smallest) whole number ratio of atoms present in a compound', where as a molecular formula is the 'actual whole number ratio of elements.'
In the future, when you calculate the empirical formula and try to find the molecular formula, you will multiply the empirical formula by positive integer, and each atom will be multiplied by this coefficient to generate the molecular formula.
Now apply this idea to your question. Which molecule is in the smallest whole number ratio?
a. C2H5 : empirical formula, because both 2 and 5 do not have a factor in common other than 1; therefore this molecule is the smallest whole number ratio.
b. C2H8: molecular formula, because both 2 and 8 have a common factor of 2; therefore the empirical formula would have been CH4.
c. CH4: empirical formula
d. C4H10: molecular formula