The formula for sucrose is C12H22O11. So there are 12 atoms of C in one molecule of sucrose. Since there are 6.022 x 1023 atoms in one mole (of anything) and you have 639 moles of the sucrose, you can find the result this way:
(12 atoms C/1 molecule sucrose)(6.022 x 1023 molecules sucrose/1 mol sucrose) 639 mol sucrose = 4.62 x 1927 atoms of C