To get the moles you need to determine the molar mass of CaCO3
Ca = 1 x 40.1 = 40.1
C = 1 x 12 = 12
O = 3 x 16 = 48
100.1 g/mol
0.500 g CaCO3 x 1 mol CaCO3 = 5.00 x 10-3 mole
100.1 g CaCO3
To find the number of formula units remember that 1 mole is equal to 6.022 x 1023 atoms
5.00 x 10-3 mol x 6.022 x 1023 atoms = 3.01 x 1021
1 mol