The neutralization reaction is given
Ba(OH)2+HCl → Ba(Cl)2 + H2O
Balance by balancing chlorine and checking other elements are balanced.
Ba(OH)2 + 2HCl → Ba(Cl)2 + 2H2O
Thus 2 moles of HCl are needed to neutralize 1 mole of Ba(OH).
Moles of HCl = 0.2 times 22.5/1000 = 0.0045 moles
This number of moles of HCl would neutralize 0.0045/2 = 0.00225 moles of Ba(OH)2
Since 150ml =.015l of Ba(OH)2 was used, the concentration is 0.00225/0.15 = 0.015M