Hello, Angie,
250 grams of H2SO3, with a molar mass of 82.1 g/mole, represents 3.05 moles of H2SO3.
The balanced equation
H2SO + O2 → H2SO3
tells us we need 1 mole of O2 for every 1 mole H2SO3. That's a molar ratio of 1/1. To produce 3.05 moles of H2SO3 we need 3.05 moles of oxygen. To find the volume of this number of moles of a gas, use the ideal gas law, PV = nRT.
Rearrange for the unknown, V:
V = nRT/P
I use a value of R, the gas constant, of 0.08206 L*atm*K-1mole-1.
Temnperature and pressure are standard, which is 1 atm pressure and 273.15K temperature. Now enter the data:
V = (3.05 moles)*(0.08206 L*atm*K-1mole-1)*(273.15K)/(1 atm)
V = 68.4 liters at STP
Bob