Hello, Sammy,
pOH and pH are the negative logs of the OH and H concentrations. So a pOH of 11.6 would mean that the concentration of OH is
[OH-] = 1x10-11.6 M
At STP, pure water is in equilibrium with it's component ions:
H2O = H+ + OH-
The equilibrium coefficient for this is 1x10-14. So we can write
1x10-14 =[H+]*[OH-]
Now we can find [H+]
1x10-14 =[H+]*[1x10-11.6]
[H+] = [1x10-11.6]/[1x10-14]
[H+] = [1x10+2.4]
The negative log of this number is 2.4
pH = 2.4
The above calculation is the fundamental relationship between pH and pOH of water. Once this is understood, it makes sense to use a much quicker approach. pH and pOH must always sum to 14 for water. If pOH is 11.6, then pH is 14 - 11.6, or 2.4.
Bob