Michael S. answered 15d
B.S. Chemistry from Indiana University - NY Regents Chemistry Tutor
They answer two different questions.
• Standard deviation (s) — how spread out your individual measurements are.
• Standard error (SE) — how precisely you know the mean of those measurements.
They are related by a single factor:
SE = s / √n
The behaviour that separates them
This is the clearest way to keep them straight: ask what happens when you collect more data.
• s does not shrink. It converges toward the true variability of whatever you are measuring. If your balance is noisy, or the objects genuinely differ, more measurements will not change that — they will just characterise it better.
• SE does shrink, as 1/√n. Averaging more measurements really does pin down the mean more tightly.
So s is a property of the thing and your method; SE is a property of your confidence in a number you computed.
How to interpret each in a lab report
Use s when describing variability: "the tablets weighed 250 mg with a standard deviation of 8 mg" tells the reader how much tablet-to-tablet variation there is, or how repeatable your technique was.
Use SE when reporting a measured value: "the concentration was 0.168 ± 0.004 M" tells the reader how well the average itself is known. A result you are asserting as the answer should carry SE (or a confidence interval), not s.
For a rough 95% confidence interval, use mean ± 2 × SE (more precisely, mean ± t × SE, with t from a table for your n).
Error bars — always say which you plotted
SE bars are always smaller than SD bars, by a factor of √n. Because of that, error bars are genuinely ambiguous unless labelled, and choosing SE purely because it looks tighter is a known bad habit in published figures. State it in the caption.
A worked feel for the numbers
Suppose five measurements give a mean of 1.063 g with s = 0.056 g.
SE = 0.056 / √5 = 0.025 g
So an individual item typically falls within about 0.056 g of the mean, but the mean is known to about 0.025 g. Report the mass as 1.063 ± 0.025 g.
The practical consequence of that square root: to halve your uncertainty in the mean you need four times as many measurements, not twice. That is why there are sharply diminishing returns on repeating a run — and why, past a point, improving your instrument (reducing s) beats collecting more data.