Hello, Robin,
The reaction follows this balanced equation:
H2SO4 + 2NaOH = Na2SO4 + 2H2O
This tells us that it takes 1 mole of sulfuric acid to neutralize 2 moles of sodium hydroxide. If we can determine the moles H2SO4 required for neutralization, that number would be doubled to determine the moles NaOH.
Find the moles H2SO4 consumed by multiplying the 2L of H2SO4 times it's molarity, 0.5M, which is defined as 0.5 moles/liter.
(2L) * (0.5 moles/L) = 1 mole H2SO4
Multiply by 2 to find the moles NaOH. That means 2 moles NaOH were present in the 3 L of the solution.
Find the concentration by division:
2moles NaOH/3 L = 0.66 M
Bob