Hello, Alexis,
Let's start by calculating the mass of N2 sought from this reaction. Take the 50.2 liters and multiply it by the density (1.25 g/L) to get 62.75 grams. Convert that to moles (62.75/28.0g/mole) = 2.24 moles of N2.
Note that it requires 2 moles of NaN3 to make 3 moles of N2. That makes it a molar ratio of (3 moles N2/2 moles NaN3). Invert that conversion to get (2 moles NaN3/3 moles N2). Multiply that times the (2.24 moles N2) requeested to find that 3.36 moles of NaN3 are required for that volume of N2 gas with a density of 1.25 g/liter.
Bob