Hello, Molly,
Use PV=nRT rearranged to
T = PV/RT
Convert 68.5 psi to atm (4.66 atm) and 84.6 ml into Liters (0.0846L)
Now we can use R = 0.08206 L*atm*K-1*mole-1 since the units (atm and L) are now consistent.
Calculate how many moles of O2 there are in 0.462 g (0.462g/32g/mole) = 0.0144 moles
Plug all the values into the equation and you'll find T = 332.8K
Bob